Sunday, June 18, 2023

Phase Behavior of Mixed Petroleum Fluids

I came across this phase diagram recently and like to explain what I see. What is this fluid, what are the likely properties, and what geological processes may have created it? I posted on LinkedIn as a question and had many good suggestions that I have incorporated in the explanation below. 

1) It is obviously a gas (vapor) reservoir by definition (reservoir temperature > critical temperature), and a retrograde one (reservoir temperature < cricondentherm), definitely not an oil. See definitions of fluid types in the blog post just below. 
2) It is not a normal retrograde condensate. First, the critical point is at -92 °C, that is colder than pure methane (perhaps some nitrogen may be mixed in there)! So it is a lean gas. The actual C6+ is only about 2 mol% - so it is actually very dry.
3) The cricondentherm (the highest temperature on the curve) for a normal dry gas should be near 0 or negative, but this one is at 380 °C! That is a cricondentherm for a black oil. High cricondentherm means it takes very high temperature to vaporize the liquid in this fluid - so it must be fairly heavy hydrocarbons. 
4) The dew point pressure is abnormally high at ~8000 psi. High Psat gas means either it has a lot of liquid (rich), and/or the liquid fraction in fluid is hard to dissolve in the gas.
5) We can rule out rich liquid case because the critical temperature is too low for that a rich condensate. 8000 psi is also too high for that too. So it is likely a mixture of a lean/dry gas with a liquid that is much heavier than normal condensate. 
6) In this particular case, it is a dry gas sourced from a coal mixed with small amount of lacustrine oils. The "condensate" is around 35 API gravity! 
7) Very high saturation pressure (some times > 12,000 psi) is a good indicator of a mixed fluid that came from very different sources. We see this in the GOM deep water, and the Mediterranean Sea, where we have mixes of biogenic gas and some normal oil. We also find these on both side of Atlantic margins, and some deep basins in China. It is one of the clues for some of the fluids offshore Guyana/Suriname.
8) This could also be a result of a dry gas with oil based mud contamination , as proposed by Brian Moffat in the LinkedIn comments section. So be careful.  

The figure below explains the effects on phase diagram when a dry/lean gas is mixed with a normal oil. 

Fig. 2. Effects of mixing dry gas with normal oil on phase diagram. Dry gas has a very low critical temperature and cricondentherm. Black oil has very high critical temperature and cricondentherm. The mixed fluid inherits the low critical temperature from the gas, but the high cricondentherm from the oil. The saturation pressure increases dramatically as the two fluids are not compatible. It takes higher pressure for them to dissolve each other.  




3 comments:

  1. Insightful exploration of petroleum fluid interactions and properties. Highly educational for professionals in the field. A valuable resource for understanding complex phase behavior.
    Freture Techno

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